Product ID:PETROLEUM ETHER 30-60 C,BL 6700,000021
MSDS Date:04/30/1993
FSC:6810
NIIN:00-584-3079
MSDS Number: BXPVC

PHILLIPS 66 COMPANY

758 ADAMS BLDG
BARTLESVILLE, OK 74004
US

Emergency Phone: 918-661-3865/8118

Info Phone: 918-661-8327/714-864-2310

Cage: 46935

PHOENIX INDUSTRIES INC

RICHMOND, VA 23222 US

Telephone: 264-5535

Cage: 0YED2

PETROLEUM ETHER 30-60 C (100%), INCLUDES THE FOLLOWING

Fraction By Weight: SEE ING

PENTANE/N-PENTANE

CAS: 109-66-0

RTECS: RZ9450000

OSHA PEL 1000 PPM

ACGIH TLV: 600 PPM/750STEL;9495

ISOHEXANE/2-METHYLPENTANE

CAS: 107-83-5

RTECS: SA2995000

3-METHYL PENTANE

CAS: 96-14-0

RTECS: SA2995500

CYCLOPENTANE

CAS: 287-92-3

RTECS: GY2390000

OSHA PEL 600 PPM

ACGIH TLV: 600 PPM; 9495

NEOHEXANE/2,2-DIMETHYLBUTANE

CAS: 75-83-2

RTECS: EJ9300000

2,3-DIMETHYLBUTANE

CAS: 79-29-8

RTECS: EJ9350000

ISOPENTANE

CAS: 78-78-4

RTECS: EK4430000

RELATED COMPONENTS

LD50 LC50 Mixture:LC50 (ORAL, RAT) >2822 PPM PETROL ETHER
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: EXPOSURE TO THE LIQUID OR
PROLONGED OVEREXPOSURE TO HIGH VAPOR CONCENTRATIONS MAY CAUSE MILD
EYE IRRITATION INCLUDING PAIN, INFLAMMATION OF THE IRIS AND MUCOUS
MEMBRANES, REDNESS AND TEARING. SK IN: PROLONGED OR REPEATED SKIN
CONTACT WITH THE LIQUID MAY CAUSE DEFATTING RESULTING IN DRYING,
REDNESS, SWELLING AND POSSIBLY BLISTERING. PROLONGED OVEREXPOSURE
TO HIGH VAPOR CONCENTRATIONS MAY CAUS E MILD MUCOUS MEMBRANE
IRRITATION. INHALATION: HIGH CONCENTRATIONS OF VAPORS MAY CAUSE CNS
DEPRESSION, UNCONSCIOUSNESS & DEATH. INGESTION:CNS DEPRESSION,
HEMORRHAGING, DIARRHEA; ASPIRATION HAZARD.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYE: MILD EYE IRRITATION INCLUDING PAIN,
INFLAMMATION OF THE IRIS AND MUCOUS MEMBRANES, REDNESS AND TEARING.
SKIN:LIQUID MAY CAUSE DEFATTING RESULTING IN DRYING, REDNESS,
SWELLING AND POSSIBLY BLISTER ING. PROLONGED OVEREXPOSURE TO HIGH
VAPOR CONCENTRATIONS MAY CAUSE MILD MUCOUS MEMBRANE IRRITATION.
INHALATION: HIGH VAPOR CONCENTRATIONS MAY CAUSE DIZZINESS,
DISORIENTATION, HEADACHE, EXCITEMENT, DR OWSINESS, INCOORDINATION,
HYPERSENSITIVITY, TREMORS HYPERACTIVITY, ANESTHESIAHEADACHE,
DIZZINESS, NAUSEA. INGESTION: CNS DEPRESSION, DIRRHEA, ASPIRATION
INTO LUNGS MAY CAUSE CHEMICAL PNEUMONITIS.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS, EYE PROBLEMS OR IMPAIRED CNS OR RESPIRATORY FUNCTION MAY
BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT.

First Aid:EYE: FLUSH EYES WITH RUNNING WATER FOR AT LEAST FIFTEEN
MINUTES. IF IRRITATION OR ADVERSE SYMPTOMS DEVELOP, SEEK MEDICAL
ATTENTION. SKIN: WASH SKIN WITH SOAP AND WATER FOR AT LEAST FIFTEEN
MINUTES. I F IRRITATION OR ADVERSE SYMPTOMS DEVELOP, SEEK MEDICAL
ATTENTION. INHALATION: REMOVE FROM EXPOSURE. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. IF BREATHING CEASES, ADMINISTER ARTIFICIAL
RESPIRATION FOLLO WED BY OXYGEN. SEEK IMMEDIATE MEDICAL ATTENTION.
INGESTION DO NOT INDUCE VOMITING. SEEK MEDICAL ATTENTION.

Flash Point:=-45.6C, -50.F
Lower Limits:1.1
Upper Limits:5.9
Extinguishing Media:FOAM, DRY CHEMICAL, CARBON DIOXIDE. DO NOT SPRAY
WATER DIRECTLY ON FIRE. PRODUCT WILL FLOAT AND COULD BE REIGNITED
ON SURFACE OF WATER.
Fire Fighting Procedures:EVACUATE AREA OF UNNECESSARY PERSONNEL. WEAR
FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED
BREATHING APPARATUS. COOL FIRE-EXPOSED CONTAINER WITH WATER. SHUT
OFF SOURCE IF POSSIBLE.
Unusual Fire/Explosion Hazard:CARBON OXIDES AND VARIOUS HYDROCARBONS
FORMED WHEN BURNED. HIGHLY FLAMMABLE VAPORS WHICH ARE HEAVIER THAN
AIR MAY ACCUMLATE IN LOW AREAS AND OR SPREAD ALONG GROUND AWAY FROM
HANDLING SITE.

Spill Release Procedures:SPILL-EVACUATE AREA OF ALL UNNECESSARY
PERSONNEL. WEAR PROTECTIVE EQUIPMENT AND/OR GARMENTS DESCRIBED IN
SECTION C IF EXPOSURE CONDITIONS WARRANT. SHUT OFF SOURCE, IF
POSSIBLE AND CONTAIN SPILL. PROT ECT FROM IGNITION. KEEP OUT OF
WATER SOURCES AND SEWERS. ABSORB IN DRY, INERT MATERIAL (SAND,
CLAY, ETC.) TRANSFER TO DISPOSAL DRUMS USING NON-SPARKING
EQUIPMENT..
Neutralizing Agent:NOT RELEVANT

Handling and Storage Precautions:AVOID CONTACT WITH EYES, SKIN OR
CLOTHING. AVOID BREATHING VAPORS, MIST, SUME OR DUST. DO NOT
SWALLOW. MAY BE ASPIRATED INTO LUNGS. WEAR PROTECTIVE EQUIPMENT OR
GARMENTS DESCRIBED IN SECTION C IF EXP OSURE CONDITIONS WARRANT.
WASH THOROUGHLY AFTER HANDLING. LAUNDER CONTAMINATED CLOTHING
Other Precautions:HIGHLY FLAMMABLE. AVOID BREATHING VAPORS. DO NOT GET
IN EYES, ON SKIN OR ON CLOTHING. WASH THOROUGHLY AFTER HANDLING AND
BEFORE EATING OR DRINKING. REMOVE CONTAMINATED CLOTHING PROMPTLY.
LAUNDER BEFOR E REUSE.

Respiratory Protection:NOT GENERALLY REQUIRED UNLESS NEEDED TO PREVENT
RESPIRATORY IRRITATION. IN CASE OF SPILL OR LEAK RESULTING IN
UNKNOWN CONCENTRATION, USE NIOSH/MSHA APPROVED SUPPLIED AIR
RESPIRATOR.
Ventilation:USE ADEQUATE VENTILATION TO CONTROL CONCENTRATION BELOW
RECOMMENDED EXPOSURE LIMITS.
Protective Gloves:USE GLOVES IMPERVIOUS TO THE MATERIAL BEING USED.
Eye Protection:USE CHEMICAL GOGGLES.
Other Protective Equipment:NO SPECIAL GARMENTS REQUIED. WEAR PROTECTIVE
EQUIPMENT AND/OR GARMENTS IF EXPOSURE CONDITIONS WARRANT.
Work Hygienic Practices:AVOID UNNECESSARY SKIN CONTAMINATION WITH
MATERIAL. WASH THOROUGHLY AFTER HANDLING. LAUNDER CONTAMINATED
CLOTHING, BEFORE REUSE.
Supplemental Safety and Health
FORMULA CHANGED. FOR PREVIOUS FORMULATIONS, SEE PNI A AND B, SAME NSN.
NOTE TO PHYSICIAN: DO NOT INDUCE VOMITING. ASPIRATION OF LIQUID
INTO THE LUNGS COULD RESULT IN CHEMICAL PNEUMONITIS. GASTRIC LAVA
GE USING A CUFFED ENDOTRACHEAL TUBE MAYBE PERFORMED AT YOUR
DESCRETION.

HCC:F2
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:=37.2C, 99.F
B.P. Text:99F - 133F
Vapor Pres:714 @ 100F
Vapor Density:2.5
Spec Gravity:0.643
Evaporation Rate & Reference:>1 (N-BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR LIQUID -MILD GASOLINE ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS AND OXYGEN
Hazardous Decomposition Products:CARBON OXIDES AND VARIOUS HYDROCARBONS
FORMED WHEN BURNED.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS. INCINERATE IN
APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINER.

Toxicological Information:IN SUBCHRONIC ORAL LABORATORY STUDIES
2-METHYLPENTANE HAS PRODUCED KIDNEY DAMAGE IN MALE RATS ONLY. NO
COMARABLE KIDNEY INJURY HAS BEEN REPORTED IN HUMANS.

Transport Information:PSN: PETROLEUM DISTILLATES, N.O.S, 3, UN1268, II.

SARA Title III Information:RCRA CLASSIFIACATION: D001 (IGNITABLE). THIS
PRODUCT DOES NOT CONTAIN A CHEMCAL OR CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 TITLE III AND 40 CFR PART
372. HAZARD CALSSIFICATION: FLAMMABLE LIQUID= YES; HEALTH HAZARD
(SEC F)=YES;
Federal Regulatory Information:THIS PRODUCT AND IT'S COMPONENTS ARE
LISTED ON THE TSCA INVENTORY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.